Fracture Properties of Graphene-Coated Silicon for Photovoltaics

authored by
Brahmanandam Javvaji, Pattabhi Ramaiah Budarapu, Marco Paggi, Xiaoying Zhuang, Timon Rabczuk
Abstract

The possibility of replacing the conductive gridline deposited on solar cells by highly electrically conductive graphene is opening new perspectives for the future generation of photovoltaics. Besides enhanced electric performance, graphene can also have a role in the resistance of silicon against cracking. Here, the influence of depositing graphene on the silicon surface, on the fracture properties of silicon, is investigated. To pin-point the influence of graphene, fracture properties estimated from molecular dynamics simulations of three different cases in uniaxial tension are compared. In the first case, the fracture properties of silicon alone are estimated in relation to different initial defect sizes. Second, the same simulations are repeated by depositing graphene on the silicon surface. Atomic interactions in the composite structure are modeled using the combined adaptive inter-molecular reactive empirical bond order (AIREBO) and Tersoff potential functions. Improvement of about 780% in the Young's modulus of silicon is achieved after coating with graphene. Furthermore, to study the influence of realistic initial defects in graphene, a third set of simulations is considered by repeating the previous tests but with initial cracks through graphene and silicon. Predictions show that graphene can be highly beneficial in strengthening and repairing micro-cracked silicon to decrease electrical power losses caused by cracks.

Organisation(s)
Institute of Continuum Mechanics
External Organisation(s)
Indian Institute of Technology Bhubaneswar (IITBBS)
IMT School for Advanced Studies Lucca
Bauhaus-Universität Weimar
Type
Article
Journal
Advanced Theory and Simulations
Volume
1
Publication date
04.12.2018
Publication status
Published
Peer reviewed
Yes
ASJC Scopus subject areas
General, Modelling and Simulation, Numerical Analysis, Statistics and Probability
Sustainable Development Goals
SDG 7 - Affordable and Clean Energy
Electronic version(s)
https://doi.org/10.1002/adts.201800097 (Access: Closed)
 

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