Reinforcing membranes with subgaskets in proton exchange membrane water electrolysis

A model-based analysis

authored by: Julian Kink, Michel Suermann, Martin Ise, Boris Bensmann, Philipp Junker, Richard Hanke-Rauschenbach
Abstract: Ensuring the long-term mechanical durability of perfluorosulfonic acid membranes in proton exchange membrane water electrolysis (PEMWE) is essential for long lifetimes. This study investigates the potential of reinforcing the membrane by incorporating a subgasket layer outside the active area. Thus, experimental tensile measurements with the subgasket material and with the subgasket-membrane composite are conducted to characterize their mechanical properties. The obtained data are used to identify suitable material models and parameterize them by applying a tensile test simulation based on the finite element method. By integrating subgaskets in a structural mechanics PEMWE cell model, the impact of the reinforcement on the membrane stability was investigated. The results indicate that even thin layers of subgaskets stabilize the membrane at the gap interface between the cell frame and the porous transport layer. The level of stabilization is further enhanced when using thicker subgaskets that cover the entire gap. However, one-sided subgaskets exhibit reduced mechanical stabilization. Furthermore, membrane buckling due to an increased gap size can be prevented using a subgasket up to a maximum gap size of 0.45 mm.
Organisation(s): Section Electrical Energy Storage Systems
Institute of Electric Power Systems
Institute of Continuum Mechanics
External Organisation(s): Siemens Energy Global GmbH & Co. KG
Type: Article
Journal: Journal of power sources
Volume: 614
ISSN: 0378-7753
Publication date: 15.09.2024
Publication status: Published
Peer reviewed: Yes
ASJC Scopus subject areas: Renewable Energy, Sustainability and the Environment, Energy Engineering and Power Technology, Physical and Theoretical Chemistry, Electrical and Electronic Engineering
Sustainable Development Goals: SDG 7 - Affordable and Clean Energy
Electronic version(s): https://doi.org/10.1016/j.jpowsour.2024.234987 (Access: Open)
: Details in the research portal "Research@Leibniz University"

BibTeX

@article{364dee29f75d428ea4e660f1ae824f52,
title = "Reinforcing membranes with subgaskets in proton exchange membrane water electrolysis: A model-based analysis",
abstract = "Ensuring the long-term mechanical durability of perfluorosulfonic acid membranes in proton exchange membrane water electrolysis (PEMWE) is essential for long lifetimes. This study investigates the potential of reinforcing the membrane by incorporating a subgasket layer outside the active area. Thus, experimental tensile measurements with the subgasket material and with the subgasket-membrane composite are conducted to characterize their mechanical properties. The obtained data are used to identify suitable material models and parameterize them by applying a tensile test simulation based on the finite element method. By integrating subgaskets in a structural mechanics PEMWE cell model, the impact of the reinforcement on the membrane stability was investigated. The results indicate that even thin layers of subgaskets stabilize the membrane at the gap interface between the cell frame and the porous transport layer. The level of stabilization is further enhanced when using thicker subgaskets that cover the entire gap. However, one-sided subgaskets exhibit reduced mechanical stabilization. Furthermore, membrane buckling due to an increased gap size can be prevented using a subgasket up to a maximum gap size of 0.45 mm.",
keywords = "Membrane, Proton exchange membrane water electrolysis, Structural mechanics investigation, Subgasket",
author = "Julian Kink and Michel Suermann and Martin Ise and Boris Bensmann and Philipp Junker and Richard Hanke-Rauschenbach",
note = "Publisher Copyright: {\textcopyright} 2024 The Authors",
year = "2024",
month = sep,
day = "15",
doi = "10.1016/j.jpowsour.2024.234987",
language = "English",
volume = "614",
journal = "Journal of power sources",
issn = "0378-7753",
publisher = "Elsevier",
}